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FeTMPyP is a synthetic porphyrin complexed with iron, which acts as a peroxynitrite decomposition catalyst. The rate constant for decomposition of peroxynitrite by FeTMPyP is 2.2 x 106 M−1s−1 with a turnover number of 360 ± 170 s−1.1 The predominant product (>90%) of this reaction is nitrate, with a minor amount of nitrite also formed (~6%), at pH 7.4.1
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1. Stern, M.K., Jensen, M.P., and Kramer, K. Peroxynitrite decomposition catalysts. Journal of the American Chemical Society 118, 8735-8736 (1996).