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Etherolenic acid is a divinyl ether oxylipin.1,2 It is a metabolite of linolenic acid that is formed in plants via 13-lipoxygenase-mediated formation of 13(S)-HpOTrE (Item No. 45220) followed by conversion to the divinyl ether by divinyl ether synthase.
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1. The lipoxygenase pathway in garlic (Allium sativum L.) bulbs: Detection of the novel divinyl ether oxylipins. FEBS Lett. 371(2), 159-162 (1995).
2. Biosynthesis of new divinyl ether oxylipins in Ranunculus plants. Lipids 37(4), 427-433 (2002).