An Analytical Reference Standard
Related Products
Certified Reference Material(s)
40618MDMB-4en-PINACA-d4 (CRM)
Unlabeled Version(s)
26097MDMB-4en-PINACA 30761MDMB-4en-PINACA (CRM)
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MDMB-4en-PINACA-d4

Item No. 36754

Restricted Product (Schedule I)
Product Insert (PDF)GC-MS (PDF)Safety Data Sheet (SDS) (PDF)
Synonyms
Synonyms
  • MDMB-PENINACA-d4
  • MDMB-PINACA N1-pentyl-4-en isomer-d4
Technical Information
Formal Name
3-methyl-N-[[1-(4-penten-1-yl)-1H-indazol-3-yl]carbonyl-d4]-L-valine, methyl ester
Molecular Formula
C20H23D4N3O3
Formula Weight
361.5
Purity
≥99% deuterated forms (d1-d4)
Formulation
A crystalline solid
Solubility(Learn about Variance in Solubility)
DMF: 12 mg/mlDMSO: 12 mg/mlEthanol: 10 mg/ml
SMILES
O=C(N[C@@H](C(C)(C)C)C(OC)=O)C1=NN(CCCC=C)C2=C1C([2H])=C([2H])C([2H])=C2[2H]
InChi Code
InChI=1S/C20H27N3O3/c1-6-7-10-13-23-15-12-9-8-11-14(15)16(22-23)18(24)21-17(19(25)26-5)20(2,3)4/h6,8-9,11-12,17H,1,7,10,13H2,2-5H3,(H,21,24)/t17-/m1/s1/i8D,9D,11D,12D
InChi Key
LWOCBHBFWNGPGM-GVCGFBQTSA-N
Regulatory Information
DEA Schedule
I
Shipping & Storage Information
Storage
-20°C
Shipping
Room temperature in continental US; may vary elsewhere
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    Product Description

    MDMB-4en-PINACA-d4 (Item No. 36754) is intended for use as an internal standard for the quantification of MDMB-4en-PINACA (Item Nos. 30761 | 26097) by GC- or LC-MS. MDMB-4en-PINACA is categorized as a synthetic cannabinoid.1 It substitutes for Δ9-THC (Item Nos. ISO60157 | 9003771 | 12068) in a drug discrimination test and induces hypothermia in mice.2 MDMB-4en-PINACA has been associated with overdose and found in samples seized by law enforcement.3,4 MDMB-4en-PINACA-d4 is regulated as a Schedule I compound in the United States. This product is intended for research and forensic applications.

    WARNING This product is not for human or veterinary use.

    References & Product Citations
    Product Description References

    1. Cannaert, A., Sparkes, E., Pike, E., et al. Synthesis and in vitro cannabinoid receptor 1 activity of recently detected synthetic cannabinoids 4F-MDMB-BICA, 5F-MPP-PICA, MMB-4en-PICA, CUMYL-CBMICA, ADB-BINACA, APP-BINACA, 4F-MDMB-BINACA, MDMB-4en-PINACA, A-CHMINACA, 5F-AB-P7AICA, 5F-MDMB-P7AICA, and 5F-AP7AICA. ACS Chem. Neurosci. 11(24), 4434-4446 (2020).

    2. Marusich, J.A., Gamage, T.F., Zhang, Y., et al. In vitro and in vivo pharmacology of nine novel synthetic cannabinoid receptor agonists. Pharmacol. Biochem. Behav. 220, 173467 (2022).

    3. Manini, A.F., Krotulski, A.J., Schimmel, J., et al. Respiratory failure in confirmed synthetic cannabinoid overdose. Clin. Toxicol. (Phila) 60(4), 524-526 (2022).

    4. Rodrigues, T.B., Souza, M.P., de Melo Barbosa, L., et al. Synthetic cannabinoid receptor agonists profile in infused papers seized in Brazilian prisons. Forensic Toxicol. 40(1), 119-124 (2022).