A byproduct in the synthesis of food dyes
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Product Type

6,6′-Oxybis(2-naphthalenesulfonate) (sodium salt)

Item No. 45595

Technical Information
Formal Name
6,6′-oxybis-2-naphthalenesulfonic acid, disodium salt
CAS Number
61551-82-4
Synonyms
  • DONS
Molecular Formula
C20H12O7S2 • 2Na
Formula Weight
Purity
≥95%
A solid
SMILES
[O-]S(=O)(C1=CC=C2C=C(OC3=CC4=CC=C(S([O-])(=O)=O)C=C4C=C3)C=CC2=C1)=O.[Na+].[Na+]
InChi Code
InChI=1S/C20H14O7S2.2Na/c21-28(22,23)19-7-3-13-9-17(5-1-15(13)11-19)27-18-6-2-16-12-20(29(24,25)26)8-4-14(16)10-18;;/h1-12H,(H,21,22,23)(H,24,25,26);;/q;2*+1/p-2
InChi Key
FBGQGMKNWOSSAG-UHFFFAOYSA-L
Shipping & Storage Information
Storage
-20°C
Shipping
Room temperature in continental US; may vary elsewhere
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    Product Description

    6,6’-Oxybis(2-naphthalenesulfonate) is a byproduct in the synthesis of FD&C Yellow No. 6 and FD&C Red No. 40 (Allura Red AC; Item No. 44514).1,2 It is formed during the synthesis of Schaeffer’s salt, an intermediate used in the synthesis of FD&C Yellow No. 6.1 6,6’-Oxybis(2-naphthalenesulfonate) is also an impurity formed in the synthesis of FD&C Yellow No. 5.3

    WARNING This product is not for human or veterinary use.

    References & Product Citations
    Product Description References

    1. Bailey, J.E., and Calvey, R.J. Spectral compilation of dyes, intermediates, and other reaction products structurally related to FD&C Yellow No. 6. J. Assoc. Off. Anal. Chem. 58(6), 1087-1128 (2020).

    2. Cox, E.A., and Reed, G.F. High performance liquid chromatographic determination of intermediates and two reaction by-products in FD&C Red No. 40: Collaborative study. J. Assoc. Off. Anal. Chem. 64(2), 324-331 (2020).

    3. Ogura, N., Nakamura, Y., Shinomiya, K., et al. Separation of impurities in commercial food Yellow No. 5 by counter alternative current chromatography and structural analyses. Anal. Sci. 11, 759-763 (1994).