An Analytical Reference Standard
Features
  • This product has been formulated as an exempt preparation which meets criteria established by the US DEA
  • Possession of a DEA Controlled Substance registration is not necessary nor is a DEA 222 form required to purchase this product
  • This product is intended to be used as an analytical reference standard
  • Bulk material is available for academic research at qualified institutions; please contact our sales department for pricing
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9(S)-Hexahydrocannabinol-d9 (exempt preparation)

Item No. 44686

Exempt Product (US)
Product Insert (PDF)Safety Data Sheet (SDS) (PDF)
Synonyms
Synonyms
  • 9α-Hexahydrocannabinol-d9
  • 11α-Hexahydrocannabinol-d9
  • 9α-HHC-d9
  • 9(S)-HHC-d9
  • 11α-HHC-d9
  • trans-(6aR,9S,10aR)-HHC-d9
Technical Information
Formal Name
6aR,7,8,9S,10,10aR-hexahydro-6,6,9-trimethyl-3-(pentyl-2,2,3,3,4,4,5,5,5-d9)-6H-dibenzo[b,d]pyran-1-ol
Molecular Formula
C21H23D9O2
Formula Weight
325.5
Purity
≥99% deuterated forms (d1-d9)
Formulation (Request formulation change)
A 100 µg/ml solution in acetonitrile
SMILES
CC1(C)[C@@]2([H])[C@](C[C@@H](C)CC2)([H])C3=C(C=C(CC([2H])([2H])C([2H])([2H])C([2H])([2H])C([2H])([2H])[2H])C=C3O)O1
InChi Code
InChI=1S/C21H32O2/c1-5-6-7-8-15-12-18(22)20-16-11-14(2)9-10-17(16)21(3,4)23-19(20)13-15/h12-14,16-17,22H,5-11H2,1-4H3/t14-,16+,17+/m0/s1/i1D3,5D2,6D2,7D2
InChi Key
XKRHRBJLCLXSGE-FHWNFKHBSA-N
Regulatory Information
DEA Exempt Notification
This product is a DEA exempt preparation of a scheduled compound - does not require DEA Controlled Substance registration or DEA 222 form. For alternate sizes please contact sales.
Shipping & Storage Information
Storage
-20°C
Shipping
Wet ice in continental US; may vary elsewhere
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    Product Description

    9(S)-Hexahydrocannabinol-d9 (exempt preparation) (Item No. 44686) is intended for use as an internal standard for the quantification of 9(S)-hexahydrocannabinol (Item Nos. 37942 | 27501) by GC- or LC-MS. 9(S)-Hexahydrocannabinol is structurally similar to known phytocannabinoids.1 It induces drowsiness, decreased motor activity, occasional partial ptosis, and occasional head drop, markers of psychotropic activity, in rhesus monkeys.2 9(S)-Hexahydrocannabinol-d9 is regulated as a Schedule I compound in the United States. 9(S)-Hexahydrocannabinol-d9 (exempt preparation) (Item No. 44686) is provided as a DEA exempt preparation. This product is intended for research and forensic applications.

    WARNING This product is not for human or veterinary use.

    References & Product Citations
    Product Description References

    1. Lee, Y.R., and Xia, L. Efficient one-pot synthetic approaches for cannabinoid analogues and their application to biologically interesting (–)-hexahydrocannabinol and (+)-hexahydrocannabinol. Tetrahedron Lett. 49(20), 3283-3287 (2008).

    2. Mechoulam, R., Lander, N., Varkony, T.H., et al. Stereochemical requirements for cannabinoid activity. J. Med. Chem. 23(10), 1068-1072 (1980).