An insecticide
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Analytical Standard(s)
39359Spinetoram (CRM)
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Spinetoram

Item No. 26623

Product Insert (PDF)Safety Data Sheet (SDS) (PDF)
Technical Information
Formal Name
(2R,3aR,5aR,5bS,9S,13S,14R,16aS,16bR)-2-[(6-deoxy-3-O-ethyl-2,4-di-O-methyl-α-L-mannopyranosyl)oxy]-13-[[(2R,5S,6R)-5-(dimethylamino)tetrahydro-6-methyl-2H-pyran-2-yl]oxy]-9-ethyl-2,3,3a,4,5,5a,5b,6,9,10,11,12,13,14,16a,16b-hexadecahydro-14-methyl-1H-as-indaceno[3,2-d]oxacyclododecin-7,15-dione and (2S,3aR,5aS,5bS,9S,13S,14R,16aS,16bS)-2-[(6-deoxy-3-O-ethyl-2,4-di-O-methyl-α-L-mannopyranosyl)oxy]-13-[[(2R,5S,6R)-5-(dimethylamino)tetrahydro-6-methyl-2H-pyran-2-yl]oxy]-9-ethyl-2,3,3a,5a,5b,6,9,10,11,12,13,14,16a,16b-tetradecahydro-4,14-dimethyl-1H-as-indaceno[3,2-d]oxacyclododecin-7,15-dione (mixture)
CAS Number
935545-74-7
Synonyms
  • XDE-175-J/XDE-175-L
Molecular Formula
C42H69NO10 • C43H69NO10
Formula Weight
1508.0
Purity
≥95% (mixture)
Formulation
A crystalline solid
Solubility(Learn about Variance in Solubility)
DMF: 30 mg/mlDMSO: 5 mg/mlEthanol: 30 mg/mlEthanol:PBS (pH 7.2) (1:3): 0.25 mg/ml
λmax
245 nm
SMILES
O=C1C2=C[C@]3([H])[C@](CC[C@@]4([H])[C@@]3([H])C[C@H](O[C@]5([H])O[C@@H](C)[C@H](OC)[C@@H](OCC)[C@H]5OC)C4)([H])[C@]2([H])CC(O[C@@H](CC)CCC[C@H](O[C@]6([H])O[C@H](C)[C@@H](N(C)C)CC6)[C@H]1C)=O.O=C7C8=C[C@]9([H])[C@](C=C(C)[C@@]%10([H])[C@@]9([H])C[C@H](O[C@]%11([H])O[C@@H](C)[C@H](OC)[C@@H](OCC)[C@H]%11OC)C%10)([H])[C@]8([H])CC(O[C@@H](CC)CCC[C@H](O[C@]%12([H])O[C@H](C)[C@@H](N(C)C)CC%12)[C@H]7C)=O
InChi Code
InChI=1S/C43H69NO10.C42H69NO10/c1-11-27-14-13-15-36(54-38-17-16-35(44(7)8)25(5)50-38)24(4)39(46)34-21-32-30(33(34)22-37(45)52-27)18-23(3)29-19-28(20-31(29)32)53-43-42(48-10)41(49-12-2)40(47-9)26(6)51-43;1-10-27-13-12-14-35(53-37-18-17-34(43(6)7)24(4)49-37)23(3)38(45)33-21-31-29(32(33)22-36(44)51-27)16-15-26-19-28(20-30(26)31)52-42-41(47-9)40(48-11-2)39(46-8)25(5)50-42/h18,21,24-33,35-36,38,40-43H,11-17,19-20,22H2,1-10H3;21,23-32,34-35,37,39-42H,10-20,22H2,1-9H3/t24-,25-,26+,27+,28-,29+,30-,31-,32-,33+,35+,36+,38+,40+,41-,42-,43+;23-,24-,25+,26-,27+,28-,29-,30-,31-,32+,34+,35+,37+,39+,40-,41-,42+/m11/s1
InChi Key
ZCQJWWOUMAIJSW-SABQUQDRSA-N
Shipping & Storage Information
Storage
-20°C
Shipping
Room temperature in continental US; may vary elsewhere
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    Product Description

    Spinetoram is an insecticide and a semisynthetic derivative of the insecticide spinosad (Item No. 25649).1 Spinetoram is a mixture of 3’-ethyl-5,6-dihydrospinosyn J and 3’-ethoxy-spinosyn L (Item No. 26664). It induces mortality in H. armigera third, fourth, and fifth instar larvae when administered in the diet at 0.19 and 0.36 mg/kg and decreases pupal survival and adult emergence in surviving larvae.2 It also induces mortality of wild-type D. melanogaster but not D. melanogaster containing a genetic mutation in the Dα6 subunit of the nicotinic acetylcholine receptor (nAChR; LC50s = 0.025 and 4.4 µg/cm2, respectively, administered in the diet).3 Formulations containing spinetoram have been used as insecticides in agriculture.

    WARNING This product is not for human or veterinary use.

    References & Product Citations
    Product Description References

    1. Kirst, H.A. The spinosyn family of insecticides: Realizing the potential of natural products research. J. Antibiot. (Tokyo) 63(3), 101-111 (2010).

    2. Wei, J., Zhang, L., Yang, S., et al. Assessment of the lethal and sublethal effects by spinetoram on cotton bollworm. PLoS One 13(9), e0204154 (2018).

    3. Watson, G.B., Chouinard, S.W., Cook, K.R., et al. A spinosyn-sensitive Drosophila melanogaster nicotinic acetylcholine receptor identified through chemically induced target site resistance, resistance gene identification, and heterologous expression. Insect Biochem. Mol. Biol. 40(5), 376-384 (2010).