An internal standard for the quantification of piperonyl butoxide
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Unlabeled Version(s)
25820Piperonyl Butoxide
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Piperonyl Butoxide-d9

Item No. 39581

Product Insert (PDF)Safety Data Sheet (SDS) (PDF)
Technical Information
Formal Name
5-((2-(2-(butoxy-d9)ethoxy)ethoxy)methyl)-6-propylbenzo[d][1,3]dioxole
CAS Number
1329834-53-8
Synonyms
  • PBO-d9
Molecular Formula
C19H21D9O5
Formula Weight
347.5
Purity
≥99% deuterated forms (d1-d9)
Formulation
A 1 mg/ml solution in acetonitrile
Solubility(Learn about Variance in Solubility)
Acetonitrile: SolubleChloroform: Slightly solubleMethanol: Slightly soluble
SMILES
CCCC1=C(COCCOCCOC([2H])([2H])C([2H])([2H])C([2H])([2H])C([2H])([2H])[2H])C=C(OCO2)C2=C1
InChi Code
InChI=1S/C19H30O5/c1-3-5-7-20-8-9-21-10-11-22-14-17-13-19-18(23-15-24-19)12-16(17)6-4-2/h12-13H,3-11,14-15H2,1-2H3/i1D3,3D2,5D2,7D2
InChi Key
FIPWRIJSWJWJAI-NPNXCVMYSA-N
Shipping & Storage Information
Storage
-20°C
Shipping
Wet ice in continental US; may vary elsewhere
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    500 µg

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    Product Description

    Piperonyl butoxide-d9 is intended for use as an internal standard for the quantification of piperonyl butoxide (Item No. 25820) by GC- or LC-MS. Piperonyl butoxide is an insecticide synergist.1,2 It inhibits cytochrome P450 (CYP) activity in western corn rootworm (D. virgifera) abdominal microsomes in a concentration-dependent manner.3 Piperonyl butoxide increases the toxicity of the pyrethroid insecticide deltamethrin (Item No. 24172) to field-collected, deltamethrin-resistant strains of the bed bug C. lectularius by 5.6- to 176-fold when used at a concentration of 50 μg/μl.2 Piperonyl butoxide also increases the toxicity of the organotin insecticide cyhexatin to fourth instar larvae of susceptible strains of the cotton leafworm S. littoralis.4 It is not toxic to the freshwater invertebrates H. azteca, C. tentans, and L. variegatus (LC50s = 530, 2,740, and 3,540 μg/L, respectively) and reduces the toxicity of the organophosphate pesticides diazinon (Item No. 23769), chlorpyrifos (Item No. 21412), and azinphos-methyl.1 Formulations containing piperonyl butoxide have been used in the control of agricultural, household, and veterinary pests.

    WARNING This product is not for human or veterinary use.

    References & Product Citations
    Product Description References

    1. Ankley, G.T., and Collyard, S.A. Influence of piperonyl butoxide on the toxicity of organophosphate insecticides to three species of freshwater benthic invertebrates. Comp. Biochem. Physiol. 110(2), 149-155 (1995).

    2. Romero, A., Potter, M.F., and Haynes, K.F. Evaluation of piperonyl butoxide as a deltamethrin synergist for pyrethroid-resistant bed bugs. J. Econ. Entomol. 102(6), 2310-2315 (2009).

    3. Scharf, M.E., Siegfried, B.D., Meinke, L.J., et al. Cytochrome P450-mediated N-demethylation activity and induction in insecticide-resistant and susceptible western corn rootworm populations (Coleoptera: Chrysomelidae). Pesicide Biochem. Physiol. 67(2), 137-143 (2000).

    4. Radwan, H.S.A., Riskallah, M.R., and El-Keie, I.A. Synergistic effects on the toxicity of organotins on cotton leafworms. Toxicology 14(3), 193-198 (1979).